Lithographic substrate and a device

ABSTRACT

A lithographic method is disclosed that includes, on a substrate provided with a layer of a resist and a further layer of a material provided on the layer of resist, providing a pattern in the further layer, the pattern defining a space via which an area of the layer of resist may be exposed to radiation, a distance between features of the pattern defining the space, and exposing the layer of resist to radiation having a wavelength greater than the distance between features of the pattern defining the space, such that near-field radiation is generated which propagates into and exposes an area of the resist.

This application is a continuation application of co-pending U.S. patentapplication Ser. No. 12/463,679, filed May 11, 2009, which claimspriority and benefit under 35 U.S.C. §119(e) to U.S. Provisional PatentApplication No. 61/071,704, entitled “Lithographic Method”, filed on May14, 2008. The content of each of the foregoing applications isincorporated herein in its entirety by reference.

FIELD

The present invention relates to a lithographic method.

BACKGROUND

A lithographic apparatus is a machine that applies a desired patternonto a target portion of a substrate. Lithographic apparatus can beused, for example, in the manufacture of integrated circuits (ICs). Inthat circumstance, a patterning device, which is alternatively referredto as a mask or a reticle, may be used to generate a circuit patterncorresponding to an individual layer of the IC, and this pattern can beimaged onto a target portion (e.g. comprising part of, one or severaldies) on a substrate (e.g. a silicon wafer) that has a layer ofradiation-sensitive material (resist). In general, a single substratewill contain a network of adjacent target portions that are successivelyexposed. Known lithographic apparatus include so-called steppers, inwhich each target portion is irradiated by exposing an entire patternonto the target portion in one go, and so-called scanners, in which eachtarget portion is irradiated by scanning the pattern through the beam ina given direction (the “scanning”-direction) while synchronouslyscanning the substrate parallel or anti-parallel to this direction.

In device manufacturing methods using a lithographic apparatus, theminimum feature size, often referred to as the critical dimension (CD),is determined by the wavelength (λ) of the exposure radiation and thenumerical aperture (NA) of the projection system used by thelithographic apparatus. Various techniques have been developed to reducethe critical dimension, and the effects of these techniques are commonlycombined into a scaling factor known as k1. The relationship between thescaling factor, the numerical aperture, the wavelength of the radiationused, and the critical dimension is as follows:

CD=k1·λ/NA

A process to obtain a reduced scaling factor comprises using near fieldimaging to expose a layer of resist, which involves the generation anduse of near-field radiation. In a known method, the near-field radiationis generated using a specifically designed mask which is independent ofa resist coated substrate to which a pattern is to be applied. In orderto use the near-field radiation to apply a pattern to the resist on thesubstrate, the mask needs to be accurately spaced apart from the resistacross all areas of the resist to be patterned, or alternatively themask needs to be brought into contact with all areas of the resist to bepatterned. In practice, it is difficult to achieve the accurateseparation between the mask and the resist that is required toaccurately apply patterns to the resist. Alternatively, if the mask isto be brought into contact with the resist, it is difficult to ensurethat all areas of the resist to be patterned are actually in contactwith the mask, and it is also possible that the mask may damage theresist when it is brought into contact with it.

SUMMARY

It is desirable to provide, for example, a lithographic method whichobviates or mitigates one or more of the problems mentioned above and/orone or more other problems. For example, it is desirable to provide, forexample, a lithographic method which does not require a near-fieldgenerating mask to be accurately spaced from a resist coated substrate,or brought into contact with the resist.

According to an aspect of the invention, there is provided alithographic method comprising, on a substrate provided with a layer ofa resist, and a further layer of a material provided on the layer ofresist: providing a pattern in the further layer, the pattern defining aspace via which an area of the layer of resist may be exposed toradiation, a distance between features of the pattern defining thespace; exposing the layer of resist to radiation having a wavelengthgreater than the distance between features of the pattern defining thespace, such that near-field radiation is generated which propagates intoand exposes an area of the resist.

In an embodiment, there is no gap between the further layer and thelayer of resist to be exposed to the near-field radiation, and so thereis no need or requirement to accurately control the gap between the twolayers. Similarly, in an embodiment, there is no need to consider how tobring the further layer into contact with an area of resist to bepatterned since the further layer is already in contact with the layerof resist since it was provided on that layer.

The material may be a metal, a second resist or a silylated resist. Themetal may be chromium.

The method may further comprise applying a silylation process to theexposed area of resist.

The method may further comprise removing the further layer. The methodmay further comprise developing or etching the resist.

Exposing the layer of resist to radiation may comprise exposing theresist to polarized radiation. Exposing the layer of resist to radiationmay comprise exposing the resist to radiation which is incident at anangle substantially normal to the layer of resist.

The method may further comprise providing the layer of resist on thesubstrate. The method may further comprise providing the further layeron the layer of resist.

According to an aspect of the invention, there is provided a device, ora part of a device, manufactured according the method described herein.

According to an aspect of the invention, there is provided a substrateprovided with: a layer of resist on the substrate; and a further layerof material on the layer of resist, the further layer provided with apattern defining a space via which an area of the layer of resist may beexposed to radiation, a distance between features of the patterndefining the space, wherein the distance between features of the patterndefining the space is arranged to be less than a wavelength of radiationto which the layer of resist is to be exposed, such that during thatexposure, near-field radiation is generated which propagates into andexposes an area of the resist.

BRIEF DESCRIPTION OF THE DRAWINGS

Embodiments of the invention will now be described, by way of exampleonly, with reference to the accompanying schematic drawings in whichcorresponding reference symbols indicate corresponding parts, and inwhich:

FIG. 1 schematically depicts an embodiment of a lithographic apparatus;

FIGS. 2 a to 2 e schematically depict process steps to provide a furtherlayer on top of a layer of resist, for use in applying a pattern to thelayer of resist, in accordance with an embodiment of the presentinvention;

FIG. 3 schematically depicts an exposure process, and associatedoperating principles, to apply a pattern to the layer of resistdescribed in relation to FIGS. 2 a to 2 e;

FIG. 4 schematically depicts the effect of exposure of the layer ofresist to near-field radiation generated by the further layer;

FIG. 5 schematically depicts pattern features that may be generated inaccordance with an embodiment of the present invention; and

FIG. 6 is a flow chart schematically depicting a lithographic processaccording to an embodiment of the present invention.

DETAILED DESCRIPTION

Although specific reference may be made in this text to the use oflithographic apparatus in the manufacture of ICs, it should beunderstood that the lithographic apparatus described herein may haveother applications, such as the manufacture of integrated opticalsystems, guidance and detection patterns for magnetic domain memories,liquid-crystal displays (LCDs), thin-film magnetic heads, etc. Theskilled artisan will appreciate that, in the context of such alternativeapplications, any use of the terms “wafer” or “die” herein may beconsidered as synonymous with the more general terms “substrate” or“target portion”, respectively. The substrate referred to herein may beprocessed, before or after exposure, in for example a track (a tool thattypically applies a layer of resist to a substrate and develops theexposed resist) or a metrology or inspection tool. Where applicable, thedisclosure herein may be applied to such and other substrate processingtools. Further, the substrate may be processed, more than once, forexample in order to create a multi-layer IC, so that the term substrateused herein may also refer to a substrate that already contains multipleprocessed layers.

The terms “radiation” and “beam” used herein encompass all types ofelectromagnetic radiation, including ultraviolet (UV) radiation (e.g.having a wavelength of 365, 248, 193, 157 or 126 nm) and extremeultra-violet (EUV) radiation (e.g. having a wavelength in the range of5-20 nm).

The term “patterning device” used herein should be broadly interpretedas referring to a device that can be used to impart a radiation beamwith a pattern in its cross-section such as to create a pattern in atarget portion of the substrate. It should be noted that the patternimparted to the radiation beam may not exactly correspond to the desiredpattern in the target portion of the substrate. Generally, the patternimparted to the radiation beam will correspond to a particularfunctional layer in a device being created in the target portion, suchas an integrated circuit.

A patterning device may be transmissive or reflective. Examples ofpatterning device include masks, programmable mirror arrays, andprogrammable LCD panels. Masks are well known in lithography, andinclude mask types such as binary, alternating phase-shift, andattenuated phase-shift, as well as various hybrid mask types. An exampleof a programmable mirror array employs a matrix arrangement of smallmirrors, each of which can be individually tilted so as to reflect anincoming radiation beam in different directions; in this manner, thereflected beam is patterned.

The term “projection system” used herein should be broadly interpretedas encompassing various types of projection system, including refractiveoptical systems, reflective optical systems, and catadioptric opticalsystems, as appropriate for example for the exposure radiation beingused, or for other factors such as the use of an immersion fluid or theuse of a vacuum. Any use of the term “projection lens” herein may beconsidered as synonymous with the more general term “projection system”.

The lithographic apparatus may be of a type having two (dual stage) ormore substrate tables (and/or two or more support structures). In such“multiple stage” machines the additional tables may be used in parallel,or preparatory steps may be carried out on one or more tables while oneor more other tables are being used for exposure.

The lithographic apparatus may also be of a type wherein the substrateis immersed in a liquid having a relatively high refractive index, e.g.water, so as to fill a space between the final element of the projectionsystem and the substrate. Immersion techniques are well known in the artfor increasing the numerical aperture of projection systems.

FIG. 1 schematically depicts a lithographic apparatus according to aparticular embodiment. The apparatus comprises:

an illumination system (illuminator) IL to condition a beam PB ofradiation (e.g, UV, DUV or EUV radiation, or radiation having an evenshorter wavelength);

a support structure (e.g. a support structure) MT to support apatterning device (e.g. a mask) MA and connected to first positioningdevice PM to accurately position the patterning device with respect toitem PL;

a substrate table (e.g. a wafer table) WT to hold a substrate (e.g. aresist-coated wafer) W and connected to second positioning device PW toaccurately position the substrate with respect to item PL; and

a projection system (e.g. a refractive projection lens) PL configured toimage a pattern imparted to the radiation beam PB by patterning deviceMA onto a target portion C (e.g. comprising one or more dies) of thesubstrate W.

As here depicted, the apparatus is of a transmissive type (e.g.employing a transmissive mask). Alternatively, the apparatus may be of areflective type (e.g. employing a programmable mirror array of a type asreferred to above).

The illuminator IL receives a beam of radiation from a radiation sourceSO. The source and the lithographic apparatus may be separate entities,for example when the source is an excimer laser. In such cases, thesource is not considered to form part of the lithographic apparatus andthe radiation beam is passed from the source SO to the illuminator ILwith the aid of a beam delivery system BD comprising for examplesuitable directing mirrors and/or a beam expander. In other cases thesource may be integral part of the apparatus, for example when thesource is a mercury lamp. The source SO and the illuminator IL, togetherwith the beam delivery system BD if required, may be referred to as aradiation system.

The illuminator IL may comprise adjusting means AM to adjust the angularintensity distribution of the beam. Generally, at least the outer and/orinner radial extent (commonly referred to as σ-outer and σ-inner,respectively) of the intensity distribution in a pupil plane of theilluminator can be adjusted. In addition, the illuminator IL generallycomprises various other components, such as an integrator IN and acondenser CO. The illuminator provides a conditioned beam of radiationPB, having a desired uniformity and intensity distribution in itscross-section.

The illumination system may encompass various types of opticalcomponents, including refractive, reflective, and catadioptric opticalcomponents to direct, shape, or control the beam of radiation, and suchcomponents may also be referred to below, collectively or singularly, asa “lens”.

The radiation beam PB is incident on the patterning device (e.g. mask)MA, which is held on the support structure MT. Having traversed thepatterning device MA, the beam PB passes through the projection systemPL, which focuses the beam onto a target portion C of the substrate W.With the aid of the second positioning device PW and position sensor IF(e.g. an interferometric device), the substrate table WT can be movedaccurately, e.g. so as to position different target portions C in thepath of the beam PB. Similarly, the first positioning device PM andanother position sensor (which is not explicitly depicted in FIG. 1) canbe used to accurately position the patterning device MA with respect tothe path of the beam PB, e.g. after mechanical retrieval from a masklibrary, or during a scan. In general, movement of the object tables MTand WT will be realized with the aid of a long-stroke module (coarsepositioning) and a short-stroke module (fine positioning), which formpart of the positioning device PM and PW. However, in the case of astepper (as opposed to a scanner) the support structure MT may beconnected to a short stroke actuator only, or may be fixed. Patterningdevice MA and substrate W may be aligned using patterning devicealignment marks M1, M2 and substrate alignment marks P1, P2.

The support structure MT holds the patterning device. It holds thepatterning device in a way depending on the orientation of thepatterning device, the design of the lithographic apparatus, and otherconditions, such as for example whether or not the patterning device isheld in a vacuum environment. The support structure MT can usemechanical clamping, vacuum, or other clamping techniques, for exampleelectrostatic clamping under vacuum conditions. The support structure MTmay be a frame or a table, for example, which may be fixed or movable asrequired and which may ensure that the patterning device is at a desiredposition, for example with respect to the projection system.

The depicted apparatus can be used in the following preferred modes:

1. In step mode, the support structure MT and the substrate table WT arekept essentially stationary, while an entire pattern imparted to thebeam PB is projected onto a target portion C in one go (i.e. a singlestatic exposure). The substrate table WT is then shifted in the X and/orY direction so that a different target portion C can be exposed. In stepmode, the maximum size of the exposure field limits the size of thetarget portion C imaged in a single static exposure.

2. In scan mode, the support structure MT and the substrate table WT arescanned synchronously while a pattern imparted to the beam PB isprojected onto a target portion C (i.e. a single dynamic exposure). Thevelocity and direction of the substrate table WT relative to the supportstructure MT is determined by the (de-)magnification and image reversalcharacteristics of the projection system PL. In scan mode, the maximumsize of the exposure field limits the width (in the non-scanningdirection) of the target portion in a single dynamic exposure, whereasthe length of the scanning motion determines the height (in the scanningdirection) of the target portion.

3. In another mode, the support structure MT is kept essentiallystationary holding a programmable patterning device, and the substratetable WT is moved or scanned while a pattern imparted to the beam PB isprojected onto a target portion C. In this mode, generally a pulsedradiation source is employed and the programmable patterning device isupdated as required after each movement of the substrate table WT or inbetween successive radiation pulses during a scan. This mode ofoperation can be readily applied to maskless lithography that utilizesprogrammable patterning device, such as a programmable mirror array of atype as referred to above.

Combinations and/or variations on the above described modes of use orentirely different modes of use may also be employed.

As described above, current methods and apparatus to reduce the minimumfeature size (i.e. critical dimension) of a pattern by reducing thescaling factor k1 have various associated problems. FIGS. 2 a to 2 edepict process steps according to an embodiment of the present inventionwhich may overcome one or more of these and/or other problems. FIGS. 2 ato 2 e depict process steps which allow the scaling factor k1 to be lessthan 0.25, thereby reducing the minimum feature size of a patternapplied to a layer of resist. More generally, FIGS. 2 a to 2 e depictprocess steps which allow features to be applied to a layer of resistwhich have dimensions which are less than the wavelength of radiation towhich the resist is exposed.

FIG. 2 a shows a substrate 2, suitable for use in lithography. Thesubstrate 2 may be, for example, the substrate described above inrelation to the apparatus of FIG. 1. FIG. 2 b shows that the substrate 2has been provided with a layer of resist 4. FIG. 2 c shows that achromium layer 6 (i.e. a further layer) has been provided on top of thelayer of resist 4. The further layer provided on top of the layer ofresist 4 may be a material other than chromium, and may be, for example,another metal, or another layer of resist or silylated resist.

FIG. 2 d shows that the chromium layer 6 is processed in order toprovide chromium pattern features 8 which are to remain on the resistlayer 4, and chromium regions 10 which are to be removed from the resistlayer 4. Chromium pattern features 8 can be created using knownlithographic processing techniques. Such techniques may involve thedeposition of a further resist layer on top of the chromium layer 6,patterning of the further resist layer using a patterned radiation beam,and subsequent development of the further layer of resist and etchingaway of the chromium regions 10 not providing the chromium patternfeatures 8. The chromium pattern features 8 may be provided bylithographically printing a line-space pattern in the chromium layer 6using 193 nm radiation.

FIG. 2 e shows the resultant chromium pattern features 8 on the layer ofresist 4. The chromium features 8 have a width of 40 nm, and areseparated from each other by 40 nm. In other words, the chromiumfeatures have a pitch of 80 nm, a width of 40 nm and therefore a dutycycle of 50%. The depicted chromium pattern features 8 have sidewallsthat are substantially perpendicular to the layer of resist 4. However,the chromium pattern features 8 may have a different shape. For example,the sidewalls may be sloping (e.g. having a retro-grade slope) in orderto focus radiation onto or into the resist.

It will be appreciated that the wavelength of radiation used to createthe 40 nm chromium pattern features 8 is described above as being 193nm. The creation of the 40 nm chromium pattern features 8, which have asmaller dimension than the wavelength of radiation used to provide thefeatures 8, may be achieved using various techniques, such as forexample, immersion lithography, double exposure and/or double patterningtechniques.

The chromium pattern features 8 are separated from one another by adistance which is less than a wavelength of radiation which is to besubsequently used to expose the layer of resist 4. The significance ofsuch a separation will be described in more detail below.

FIG. 3 shows the chromium pattern features 8 and underlying resist layer4 being exposed to a flood exposure at normal incidence, for example TMpolarized radiation having a wavelength of 436 nm. The TM polarizedradiation is polarized in a direction parallel to the width of thepattern features 8 (i.e. perpendicular to lines defined by the widthextending into/out of the plane of FIG. 3). This exposure of thechromium pattern features 8 and underlying layer of resist 4 isundertaken using radiation 12 having a wavelength which is longer thanthe distance between adjacent chromium pattern features 8, which in thisparticular example is 40 nm. Generally speaking, radiation does not passthrough an aperture having a size which is smaller than the wavelengthof the radiation. However, due to the space between the chromium patternfeatures 8 being less than the wavelength of the flood exposureradiation 12, near-field radiation 14 is generated which leaks slightlyin the vicinity of the spaces between the chromium pattern features 8.The near-field radiation comprises a propagating part and anon-propagating part (i.e., an evanescent part), and is present in thevicinities of the spaces between the chromium pattern features 8 at adistance of about 100 nm or less from those spaces. The near-fieldradiation 14 attenuates significantly as the distance into the resistlayer 4 increases.

The near-field radiation 14 exposes areas of the resist layer 4 betweenthe chromium pattern features 8. It will be appreciated that despite theflood exposure radiation 12 having a wavelength more than ten timesgreater than the separation between the chromium pattern features 8,underlying areas of the resist layer 4 can still be exposed to theradiation 12 due to the generation and propagation of near-fieldradiation 14 in the resist layer 4.

Areas of the layer of resist 4 located in the spaces between thechromium pattern features 8 are not uniformly exposed to the near-fieldradiation 14. This is because the near-field radiation 14 effectivelycreeps along the side walls of the chromium pattern features 8 beforepropagating into and exposing an area of resist 4 adjacent to the sidewalls. Such non uniform exposure of the areas of the layer of resist 4in the spaces in between the chromium pattern features 8 is shown inFIG. 4. FIG. 4 shows a part of the substrate 2, layer of resist 4, andchromium pattern features 8 shown in and described with reference toFIG. 3. A graph 16 shows how the modeled intensity of the near-fieldradiation 14 is distributed at different depths z in the resist, and howthe distribution varies in the x-direction (which is left to right asshown in FIG. 4).

Because the near-field radiation 14 creeps along and down the side wallsof the chromium pattern features 8, it can be seen that the intensity ofthe near-field radiation 14 is highest in the area adjacent to and belowthe side walls. As the near-field radiation 14 propagates deeper intothe layer of resist 4, the exposure (i.e. the intensity) becomes moreuniform. It can be seen from the graph 16 that at a depth of around 2 nmfrom an upper surface of the layer of resist 4, and in the vicinity ofthe side walls of the chromium pattern features 8, the intensity of thenear-field radiation 14 is high, and falls away rapidly as the intensityis measured further away from the side walls in the x-direction. It canbe seen from the graph 16 that this means that down to a depth of around2 nm to 3 nm very narrow regions 420 of resist are exposed above athreshold exposure intensity 410 by the near-field radiation 14. Fromthe graph 16, it can be seen that the width of this regions 420 is lessthan 10 nm, which is over nineteen times less than the wavelength of the193 nm radiation used to pattern the chromium layer 6. Thus, thereduction of the critical dimension of pattern features applied to alayer of resist as obtained with the process shown in and described withreference to FIGS. 2 to 4 can effectively reduce the scaling factor k1to a value below 0.25.

It can also be seen from the graph 16 that a peak in the intensity ofthe near-field radiation 14 in the layer of resist 4 occurs at thelocation of each side wall of the chromium pattern features 8. For everychromium pattern feature 8, there are two side walls, and therefore twosub-10 nm regions 420 exposed above threshold to the near-fieldradiation 14. Thus, regions 420 of resist 4 exposed to the near-fieldradiation 14 form a pattern having double the pitch of the pattern ofchromium pattern features 8.

If it is desirable to develop the layer of resist 4 in order to createpattern features having dimensions less than 10 nm, as described above,it may be desirable to apply a silylation to the areas of resist locatedbetween the chromium pattern features 8 in order to provide a pattern ofsilylated resist. Such a silylation process may be useful to ensure thatit is possible to develop the resist, despite the fact that it is onlybeen exposed to a depth of around, for example, 2 nm-3 nm. On the otherhand, if the development of resist to obtain the sub-10 nm features isnot required, such a silylation process may not be required. In thiscase, it may be possible to develop the areas of resist exposed to thenear-field radiation, and not just the uppermost 2 nm of the layer ofresist 4. In this case, the pattern features in the layer of resist 4would have the same pitch and correspond to the pattern of the chromiumpattern features 8.

FIG. 5 shows the substrate provided with a plurality of sub-10 nm resistpattern features 18 provided thereon. The sub-10 nm resist patternfeatures 18 have been provided by applying the patterning, exposure andsilylation processes discussed above, removing the chromium patternfeatures and etching or developing the resist layer 4.

It will be appreciated that in comparison with known near-field exposureapparatus and methods, an embodiment of the present invention isadvantageous. This is because there is no need to: create an independentnear field mask to generate near-field radiation; accurately control agap between this mask and a layer of resist; or accurately control acontact area between the mask and the layer of resist. This is becausethe layer of chromium (or other metal or resist) deposited on the layerof resist generates the required near-field radiation to which theresist is to be exposed. There is no gap between the chromium layer andthe layer of resist to be exposed to the near-field radiation, so thereis no need or requirement to accurately control the gap between the twolayers. Similarly, there is no need to consider how to bring thechromium layer into contact with an area of resist to be patterned sincethe chromium layer is already in contact with the layer of resist sinceit was deposited on that layer.

In the above embodiments certain wavelengths of radiation, and alsodimensions and separations of pattern features have been described. Itwill however be appreciated that other dimensions are possible. Forinstance the chromium layer (or other metal or resist layer) depositedon top of the resist layer to be exposed to near-field radiation can bepatterned using radiation of any suitable wavelength, and is notrestricted to being 193 nm. Similarly, the flood exposure undertaken togenerate the near-field radiation may be any suitable wavelength, and isnot restricted to being 436 nm. The flood exposure may compriseunpolarized radiation. The flood exposure may not be normally incidentto the resist, but may be incident at another angle, for example a fewdegrees away from being normally incident. Furthermore, the patternfeatures provided in the chromium layer (or other metal layer or resistlayer) do not need to be 40 nm in width, or separated by 40 nm. Thepattern features need only be separated by a distance which is less thana wavelength of radiation used to expose the chromium layer in asubsequent flood exposure.

FIG. 6 is a flow chart 20 schematically depicted in process steps inaccordance with an embodiment of the present invention. The flow chart20 provides a summary of the embodiments described above. In a firststep 22 a layer of resist is applied to a substrate. In a second step 24a layer of, for example, chromium, is deposited on the layer of resist.In a third step 26 a pattern is then lithographically applied in the,for example, chromium layer. The pattern defines spaces which have awidth smaller than a wavelength of radiation used to expose the chromiumlayer in a subsequent part of the process, as described above. In afourth step 28 the spaces in the chromium pattern are then exposed to aradiation having a wavelength greater than the width of the spaces inthe pattern. Near-field radiation is generated, which exposes the resistlocated in the spaces. Next, and if it is desirable to extract featuresfrom the layer of resist which have only been predominantly exposed inthe uppermost few nanometers of the resist, a fifth step 30 isundertaken which involves applying a silylation process to the exposedareas of resist. In a sixth step 32, the chromium pattern is thenremoved. Finally, in a seventh step 34 the resist is developed and/oretched to form features which have a dimension (e.g. width) which issmaller than the wavelength used to expose the resist layer.

In an embodiment, there is provided a lithographic method comprising, ona substrate provided with a layer of a resist, and a further layer of amaterial provided on the layer of resist: providing a pattern in thefurther layer, the pattern defining a space via which an area of thelayer of resist may be exposed to radiation, a distance between featuresof the pattern defining the space; and exposing the layer of resist toradiation having a wavelength greater than the distance between featuresof the pattern defining the space, such that near-field radiation isgenerated which propagates into and exposes an area of the resist.

In an embodiment, the material is a metal, a second resist or asilylated resist. In an embodiment, the metal is chromium. In anembodiment, the method further comprises applying a silylation processto the exposed area of resist. In an embodiment, the method furthercomprises removing the further layer. In an embodiment, the methodfurther comprises developing or etching the resist In an embodiment,exposing the layer of resist to radiation comprises exposing the resistto polarized radiation. In an embodiment, exposing the layer of resistto radiation comprises exposing the resist to radiation which isincident at an angle substantially normal to the layer of resist. In anembodiment, the method further comprises providing the layer of resiston the substrate. In an embodiment, the method further comprisesproviding the further layer on the layer of resist.

In an embodiment, there is provided a substrate having: a layer ofresist on the substrate; and a further layer of material on the layer ofresist, the further layer having a pattern defining a space via which anarea of the layer of resist may be exposed to radiation, a distancebetween features of the pattern defining the space, wherein the distancebetween features of the pattern defining the space is arranged to beless than a wavelength of radiation to which the layer of resist is tobe exposed, such that during that exposure, near-field radiation isgenerated which propagates into and exposes an area of the resist. In anembodiment, the material is a metal, a second resist or a silylatedresist. In an embodiment, the metal is chromium.

In an embodiment, there is provided a device, or a part of a device,manufactured according to a method comprising, on a substrate providedwith a layer of a resist, and a further layer of a material provided onthe layer of resist: providing a pattern in the further layer, thepattern defining a space via which an area of the layer of resist may beexposed to radiation, a distance between features of the patterndefining the space; and exposing the layer of resist to radiation havinga wavelength greater than the distance between features of the patterndefining the space, such that near-field radiation is generated whichpropagates into and exposes an area of the resist.

In an embodiment, the material is a metal, a second resist or asilylated resist. In an embodiment, the metal is chromium. In anembodiment, the method further comprises applying a silylation processto the exposed area of resist. In an embodiment, exposing the layer ofresist to radiation comprises exposing the resist to polarizedradiation.

While specific embodiments of the invention have been described above,it will be appreciated that the invention may be practiced otherwisethan as described. For example, the invention may take the form of acomputer program containing one or more sequences of machine-readableinstructions describing a method as disclosed above, or a data storagemedium (e.g. semiconductor memory, magnetic or optical disk) having sucha computer program stored therein.

The descriptions above are intended to be illustrative, not limiting,Thus, it will be apparent to those skilled in the art that modificationsmay be made to the invention as described without departing from thescope of the claims set out below.

1. A lithographic method comprising, on a substrate provided with alayer of a resist, and a further layer of a material provided on thelayer of resist: providing a pattern in the further layer, the patterndefining a space via which an area of the layer of resist may be exposedto radiation, a distance between features of the pattern defining thespace; exposing the layer of resist to radiation having a wavelengthgreater than the distance between features of the pattern defining thespace, such that near-field radiation is generated which propagates intoand exposes an area of the resist.
 2. The lithographic method of claim1, wherein the material is a metal, a second resist or a silylatedresist.
 3. The lithographic method of claim 2, wherein the metal ischromium.
 4. The lithographic method of claim 1, further comprisingapplying a silylation process to the exposed area of resist.
 5. Thelithographic method of claim 1, further comprising removing the furtherlayer.
 6. The lithographic method of claim 5, further comprisingdeveloping or etching the resist.
 7. The lithographic method of claim 1,wherein exposing the layer of resist to radiation comprises exposing theresist to polarized radiation.
 8. The lithographic method of claim 1,wherein exposing the layer of resist to radiation comprises exposing theresist to radiation which is incident at an angle substantially normalto the layer of resist.
 9. The lithographic method of claim 1, furthercomprising providing the layer of resist on the substrate.
 10. Thelithographic method of claim 9, further comprising providing the furtherlayer on the layer of resist.
 11. A substrate having: a layer of resiston the substrate; and a further layer of material on the layer ofresist, the further layer having a pattern defining a space via which anarea of the layer of resist may be exposed to radiation, a distancebetween features of the pattern defining the space, wherein the distancebetween features of the pattern defining the space is arranged to beless than a wavelength of radiation to which the layer of resist is tobe exposed, such that during that exposure, near-field radiation isgenerated which propagates into and exposes an area of the resist. 12.The substrate of claim 11, wherein the material is a metal, a secondresist or a silylated resist.
 13. The substrate of claim 12, wherein themetal is chromium.
 14. A device, or a part of a device, manufacturedaccording to a method comprising, on a substrate provided with a layerof a resist, and a further layer of a material provided on the layer ofresist: providing a pattern in the further layer, the pattern defining aspace via which an area of the layer of resist may be exposed toradiation, a distance between features of the pattern defining thespace; exposing the layer of resist to radiation having a wavelengthgreater than the distance between features of the pattern defining thespace, such that near-field radiation is generated which propagates intoand exposes an area of the resist.
 15. The device of claim 14, whereinthe material is a metal, a second resist or a silylated resist.
 16. Thedevice of claim 15, wherein the metal is chromium.
 17. The device ofclaim 14, wherein the method further comprises applying a silylationprocess to the exposed area of resist.
 18. The device of claim 14,wherein exposing the layer of resist to radiation comprises exposing theresist to polarized radiation.